1. An advocate was arranged by the police for your brother. This is news to me. Police does not arrange a lawyer for a person. The concerned accused has the right to engage a lawyer of his own choice. Your brother should have engaged his own lawyer instead of engaging the one which was arranged by the police. The motive of the police to arrange a lawyer for your brother is highly questionable.
2. If your brother has paid the briefing and appearance fee till now to his lawyer the latter is bound to give a NOC.
3. The courts in most parts of the country do not allow another lawyer to be engaged, and rightly so, unless a NOC from the previous lawyer has been obtained. However, your brother may complain to the District Judge that his lawyer is deliberately withholding the NOC in spite of his fee having been paid.